Membrane Capacitive Deionization Research Articles

Efficient removal of short-chain perfluoroalkyl substances (PFAS) using asymmetric membrane capacitive deionization

Concerns have been raised over the persistence and potential health risks of perfluoroalkyl substances (PFAS). PFAS pose significant challenges in water treatment owing to their chemical stability and the difficulty of treating them with conventional purification methods. Although traditional water treatment methods for contaminant removal have been explored, their effectiveness against PFAS remains limited. This gap in knowledge highlights the need for innovative approaches. This study introduces asymmetric membrane capacitive deionization (ACDI) as a novel method for short-chain PFAS removal to address the shortcomings of existing techniques. ACDI refers to a configuration in which an anion exchange membrane is removed from a conventional membrane capacitive deionization with both a cation exchange membrane and an anion exchange membrane. Among the PFAS, perfluorobutanesulfonic acid (PFBS), which is known to be difficult to remove because of its short chain, has been the focus. The ACDI system demonstrated superior deionization capacity (28.75 mg/g) and energy efficiency (energy consumption of 0.46 Wh/g) compared to conventional CDI and membrane CDI systems. In addition, the effects of key operating parameters, such as voltage (0.5 ∼ 1.2 V), initial concentration (50 ∼ 500 mg/L), and flow rate (1 ∼ 5 mL/min), on the PFBS removal were systematically investigated and superior at 1.2 V, 500 mg/L, and 2 mL/min. This study suggests the need for further exploration of real-world applications considering the presence of competing ions in wastewater. This study provides valuable insights into advancing CDI technology for the sustainable treatment of industrial wastewater containing PFAS.

Capacitive deionization electrode fabrication using activated carbon derived from agriculture by-products toward industry application: A review

Capacitive deionization (CDI), membrane capacitive deionization (MCDI), and flow capacitive deionization (FCDI) are emerging technologies applied to remove ions from brackish water or saline wastewater based on electrode double layer (EDL) mechanisms. The electrode itself can be seen as the most important factor that determines the deionization efficiency of the CDI system. Electrode fabrication using activated carbon derived from agriculture byproducts is a useful solution to decrease cost, restrict environmental pollution, and enable agriculture waste recovery. In this review, the primary parameter's impact on activated carbon (AC) and the electrode fabrication process from the agriculture byproducts is detailed in a discussion to find the most optimal conditions. With excellent characteristics for the activated carbon such as a surface area of up to 2500 m2/g, it can be used to fabricate electrodes that have a high adsorption capacity of approximately 25 mg/g, able to be advanced to 40 mg/g with a modified AC. It can achieve a cycle performance of 95-97%. The deionization efficiency of the CDI, MCDI, and FCDI systems can be up to 90% with an input salt concentration from 2000 to 3000 mg/L where the water recovery ratio achieved is 50-90%, alongside a salt rejection rate of about 7-75%. AC can be modified to increase its special properties such as surface area, conductivity, and ion selectivity using different methods. The drawbacks and challenges of the CDI technology are also mentioned along with useful solutions such as electrode coating techniques using an anilox roller and a spray, for use in industry applications.

Scaling behavior of Si in capacitive deionization (CDI) systems for brackish groundwater desalination

Capacitive deionization (CDI) is a potentially cost-effective method of desalinating brackish groundwaters though the technology has not yet been widely utilised for this particular application. Silicon (Si) is a common element in groundwaters which may cause problems due to its tendency to induce severe fouling of equipment used for water treatment. In this study we focus on the impacts of the presence of Si on the performance of CDI. A systematic evaluation procedure is proposed, which is used to distinguish the “dynamic” and residual Si scaling and the impacts of these types of fouling on desalination performance. Results show that Si has minimal influence on CDI performance within low concentration ranges (<0.5 mM). Sorption of deprotonated silicic acid species is largely avoided in CDI, which contributes to sustaining the removal of major ions and stable operation of the system. However, at high concentrations of Si (>2.0 mM), scaling was observed to form on the electrode surface, leading to noticeable deterioration in CDI electrode performance. The presence of ion exchange membrane in CDI (i.e., membrane CDI or MCDI) can significantly alleviate Si scaling of the desalination system. Results of this study clearly demonstrate the scaling behavior of CDI and its derivatives when dealing with Si-laden water matrices, providing insights into the design and maintenance of CDI systems in practical applications.

A single-electrode evaluation method used for analyzing the working mechanism and capability of integrated membrane capacitive deionization

The evaluation of capacitive deionization (CDI) often relies on indicators like salt adsorption capacity and rate. However, these indicators encompass the entire system, including the anode and cathode. In practice scenarios, differences in specific capacitance, weight, and potential of zero charge result in varying theoretical ion adsorption capacity (IAC) and electrode potential. Hence, it is crucial to assess the deionization performance of individual electrodes. In this study, by introducing a reference electrode into the desalination device and enhancing the effective area and mass loading of the counter electrode, a single-electrode evaluation device was established to specifically analyze the deionization performance of the working electrode. Through this evaluation method, the single-electrode deionization performances of the anodic and cathodic integrated membrane electrodes (IMEs) were investigated, respectively, shedding light on the impact of IME on the Faradaic side reactions and co-ion effect. The results indicate that IME maintains an effective working voltage window and improves its stability. The cathodic IME effectively curbs the transport of dissolved oxygen, and the anodic IME prevents the carbon oxidation, thereby bolstering their IACs. This research not only elucidates the operational mechanism of IME but also highlights the feasibility of the single-electrode evaluation strategy in appraising asymmetric CDI.

Constructing ionic highway in capacitive deionization via integrated electrodes based on bifunctional ionomer

In this work, bifunctional ionomeric capacitive deionization (BICDI) electrode are constructed by using bifunctional ionomer as electrode binder and ion exchange material for the enhancement of desalination performance. Compared with traditional membrane capacitive deionization (MCDI) electrodes, the BICDI electrodes were fabricated by using the poly(arylene alkylene) based ionomer to substitute the PVDF binder and ion exchange membrane (IEM). The BICDI electrode based on bifunctional ionomer exhibits higher hydrophilicity, special ion exchange capability, as well as excellent electrochemical properties in comparsion with that of MCDI electrode counterpart. The built-in ionic groups in poly(arylene alkylene) based ionomers could create interconnected ionic highway between different electrode particles, which encourages effective ion transport. The desalination results validated that the salt adsorption capacity (SAC) of carbon-based BICDI electrodes reached 19.2 mg g−1, which is 2.2 times that of MCDI electrodes during adsorption-desorption cycles. Meanwhile, BICDI electrode possesses exceptional charge efficiency (96.6 %), which is much higher than that of MCDI (76.8 %). In the case of BICDI device, the ionomer utilization rate increased by a factor of 88 compared to that of ion exchange membrane in MCDI device. Especially, the economic cost of the integrated BICDI electrodes module is only $35 m−2, which is much cheaper than that in conventional MCDI system ($520 m−2). It is reasonable to believe that the integrated BICDI electrode incorporated with charged bifunctional ionomer proposed in this work provide novel insights and strategies for the high-performance and large-scale CDI applications.

Integration of capacitive deionization and forward osmosis for high water recovery and ultrapure water production: concept, modelling and performance analysis

ABSTRACT Forward Osmosis (FO), a membrane desalination technology and Capacitive Deionization (CDI), an electrically operated desalination technology, are numerically integrated utilizing four different configurations for the high-water recovery rate and ultrapure water production from brackish water resource. To minimize the wastewater rejection, the CDI desorption stream is continuously fed to the FO unit, efficiently recovering the remaining freshwater. To produce ultrapure water, freshwater stream obtained from FO is provided to the CDI cell, which adsorbs the remaining dissolved solute particles. These two configurations serve the purpose of both industrial as well as domestic water supply requirements. Continuing this concept, the formation of the other two configurations allows us to obtain fresh water and ultrapure water simultaneously and up to a 90% freshwater recovery rate for the areas with inadequate supply. The performance parameters to assess the integration are the Water Recovery Rate (WRR) and Specific Energy Consumption (SEC). The first configuration (CDI-FO), proposed for a high freshwater recovery rate, resulted in 79.33% WRR with an SEC of 0.689 kWh / m 3 . While, for the second configuration (FO-CDI), 34.25% water was recovered as 2.87 ppm ultrapure water along with 34.25% freshwater. The third proposed configuration (CDI-FO-CDI) had a WRR of 79.33%, 14.67% of which was recovered as ultrapure water of concentration 2.86 ppm. The fourth configuration (CDI-FO-FO) developed for high water recovery, removed the maximum of water from the feed stream with a WRR of 91.33% and remained energy-efficient, consuming an SEC of 0.908 kWh / m 3 .

Mitigation of mineral scaling in membrane capacitive deionization – Understanding the role of pH changes and carbonates

Mineral scaling in water desalination is caused by the precipitation of salts, which is affected by various factors such as the presence of specific ions, solution pH, and temperature. While extensively researched in technologies like reverse osmosis (RO), understanding mineral scaling in membrane capacitive deionization (MCDI) remains limited. During MCDI operation, the pH of the effluent fluctuates, potentially triggering mineral scaling. The present study investigates how the adsorption and desorption of HCO3− ions and the distribution of dissolved inorganic carbon (DIC) species (H2CO3, HCO3−, and CO32−) drive pH changes. We examine mineral scaling formation at various water recoveries during MCDI operation using different thicknesses of the anion exchange membrane (AEM). Our findings indicate that pH changes increase with higher water recoveries and that increasing the AEM thickness provides a pathway to enhance MCDI stability, consequently lowering the need for anti-scaling agents.

Brackish groundwater desalination by constant current membrane capacitive deionization (MCDI): Results of a long-term field trial in Central Australia

A long-term field trial of membrane capacitive deionization (MCDI) was conducted in a remote community in the Northern Territory of Australia, with the aim of producing safe palatable drinking water from groundwater that contains high concentrations of salt and hardness ions and other contaminants. This trial lasted for 1.5 years, which, to our knowledge, is one of the longest reported studies of pilot-scale MCDI field trials. The 8-module MCDI pilot unit reduced salt concentration to below the Australian Drinking Water Guideline value of 600 mg/L total dissolved solids (TDS) concentration with a relatively high water recovery of 71.6 ± 8.7 %. During continuous constant current operation and electrode discharging at near zero volts, a rapid performance deterioration occurred that was primarily attributed to insufficient desorption of multivalent ions from the porous carbon electrodes. Performance could be temporarily recovered using chemical cleaning and modified operating procedures however these approaches could not fundamentally resolve the issue of insufficient electrode performance regeneration. Constant current discharging of the electrodes to a negative cell cut-off voltage was hence employed to enhance the stability and overall performance of the MCDI unit during the continuous operation. An increase in selectivity of monovalent ions over divalent ions was also attained by implementing negative voltage discharging. The energy consumption of an MCDI system with a capacity of 1000 m3/day was projected to be 0.40∼0.53 kWh/m3, which is comparable to the energy consumption of electrodialysis reversal (EDR) and brackish water reverse osmosis (BWRO) systems of the same capacity. The relatively low maintenance requirements of the MCDI system rendered it the most cost-efficient water treatment technology for deployment in remote locations. The LCOW of an MCDI system with a capacity of 1000 m3/day was projected to be AU$1.059/m3 and AU$1.146/m3 under two operational modes, respectively. Further investigation of particular water-energy trade-offs amongst MCDI performance metrics is required to facilitate broader application of this promising water treatment technology.

Deionization performance, desalination enhancement mechanism, desorption behavior and energy consumption analysis of biochar-based membrane capacitive deionization

Four different configurations of capacitive deionization (CDI) were assembled to comparatively investigate the contribution of different ion exchange membranes (IEMs), including anion exchange membrane (AEM) and cation exchange membrane (CEM), to the enhancement of desalination performance. The results showed that the low charge efficiency of membrane-free biochar-based CDI system was mainly attributed to co-ion repulsion rather than Faraday reactions, and a single IEM was not effective in suppressing the co-ion repulsion effect thereby exhibiting a similar low charge efficiency. Compared with AEM, CEM was more beneficial for high coulombic efficiency by restraining the oxygen reduction reactions. In addition, the electrosorption and desorption behaviors of the biochar-based membrane capacitive deionization (MCDI) under different operating conditions were explored. The results showed that zero voltage desorption (ZVD) was unfavorable to the desorption capacity of the electrode, especially in high concentration solutions, the reverse voltage desorption (RVD) led to higher desorption efficiency but required higher energy consumption. Therefore, energy consumption and regeneration efficiency need to be a trade-off in practical applications to realize energy saving and efficient desalination.

Membrane‐assisted capacitive deionization: Effect of Poly(vinyl alcohol) cross‐linking on the properties of ion exchange membranes

AbstractNovel composite electrodes were developed for application in membrane capacitive deionization (MCDI). Activated carbon (AC) was dispersed in a solution of poly(vinyl alcohol) (PVA) mixed with polyacrylic acid (PAA) or poly dimethyl diallyl ammonium chloride (PDMDAAC), and cast onto the surface of an AC‐based modified graphite electrode, prepared by phase inversion, to form a composite membrane further cross‐linked with glutaraldehyde (GA). The effect of the cross‐linking on the chemical structure of the PVA‐based membranes was determined by attenuated total reflectance Fourier‐transform infrared (ATR‐FTIR) spectroscopy. Cyclic voltammetry was conducted to examine the specific capacitance of the composite electrodes. Desalination experiments were then performed with MCDI unit cells to study the effect of cross‐linking on the desalination efficiency. It was proved that after optimization, the synthesized composite electrodes exhibited one and a half times higher NaCl removal capacity and three times higher adsorption rate as compared to that of a conventional CDI cell using commercial ion exchange membranes (IEMs) with almost the same energy consumption. The enhanced desalination performance was attributed to the optimized properties of the selected polymers and the improved adhesion of IEMs to the electrodes. This research paves the way for the application of new materials in MCDI processes for improved water desalination.

Desalting Plasma Protein Solutions by Membrane Capacitive Deionization.

Plasma protein therapies are used by millions of people across the globe to treat a litany of diseases and serious medical conditions. One challenge in the manufacture of plasma protein therapies is the removal of salt ions (e.g., sodium, phosphate, and chloride) from the protein solution. The conventional approach to remove salt ions is the use of diafiltration membranes (e.g., tangential flow filtration) and ion-exchange chromatography. However, the ion-exchange resins within the chromatographic column as well as filtration membranes are subject to fouling by the plasma protein. In this work, we investigate the membrane capacitive deionization (MCDI) as an alternative separation platform for removing ions from plasma protein solutions with negligible protein loss. MCDI has been previously deployed for brackish water desalination, nutrient recovery, mineral recovery, and removal of pollutants from water. However, this is the first time this technique has been applied for removing 28% of ions (sodium, chloride, and phosphate) from human serum albumin solutions with less than 3% protein loss from the process stream. Furthermore, the MCDI experiments utilized highly conductive poly(phenylene alkylene)-based ion exchange membranes (IEMs). These IEMs combined with ionomer-coated nylon meshes in the spacer channel ameliorate Ohmic resistances in MCDI improving the energy efficiency. Overall, we envision MCDI as an effective separation platform in biopharmaceutical manufacturing for deionizing plasma protein solutions and other pharmaceutical formulations without a loss of active pharmaceutical ingredients.

Emerging Frontiers in Multichannel Membrane Capacitive Deionization: Recent Advances and Future Prospects.

Capacitive deionization (CDI) has emerged as a promising desalination technology and recently promoted the development of multichannel membrane capacitive deionization (MC-MCDI). In MC-MCDI, the independent control of multiflow channels, including the feed and electrolyte channels, enables the optimization of electrode operation in various modes, such as concentration gradients and reverse voltage discharge, facilitating semicontinuous operation. Moreover, the integration of redox couples into MC-MCDI has led to advancements in redox-mediated desalination. Specifically, the introduction of redox-active species helps enhance the ion removal efficiency and reduce energy consumption during desalination. This systematic approach, combining principles from CDI and electrodialysis, results in more sustainable and efficient desalination. These advancements have contributed to improved desalination performance and practical feasibility, rendering MC-MCDI an increasingly attractive option for addressing water scarcity challenges. Despite the considerable interest in and potential of this process, there is currently no comprehensive review available that covers the operational features and applications of MC-MCDI. Therefore, this Review provides an overview of recent research progress, focusing on the unique cell configuration, vital operation principles, and potential advantages over conventional CDI. Additionally, innovative applications of MC-MCDI are discussed. The Review concludes with insights into future research directions, potential opportunities in industrial desalination technology, and the fundamental and practical challenges for successful implementation.

Environmental and Economic Assessment of Membrane Capacitive Deionization (MCDI) and Low-Pressure Reverse Osmosis (LPRO) for Sustainable Irrigation in the Mediterranean Region

Ensuring the sustainability of a product or a system requires a thorough evaluation of its environmental and socioeconomic impacts. In this context, one of the objectives of the EU-PRIMA SmaCuMed project is to evaluate the socioeconomic and environmental impacts of the Smart Cube system. The Smart Cube was developed for the PV-powered desalination of brackish groundwater with membrane capacitive deionization (MCDI) and low-pressure reverse osmosis (LPRO); it additionally uses smart sensors for controlled irrigation in remote agricultural areas in Morocco, as an example for the North African region. Based on the Life Cycle Sustainability Assessment approach, this paper aims to assess the environmental and economic impacts of the Smart Cube, using Life Cycle Costing (LCC) and Life Cycle Assessment (LCA) analyses for environmental evaluation. Various scenarios have been defined for both environmental and economic assessments. Based on 1 m3 of produced desalinated water, the LCC results showed that, when using the desalination technologies directly connected to the grid, the prices are lower than those obtained when it was supplied by the PV system. This is only due to the very low energy prices from the Moroccan grid (EUR 0.10/kWh). The LCC results showed that LPRO is a more cost-effective option for producing desalinated water, with a lower total cost compared to MCDI. However, LCA results indicated that LPRO has a higher environmental impact compared to MCDI. If higher water production capacity is a priority, MCDI connected to PV is the best choice, with lower carbon emission but higher overall water costs.

Sustained Phosphorus Removal and Enrichment through Off-Flow Desorption in a Reservoir of Membrane Capacitive Deionization.

In this study, we used a membrane capacitive deionization device with a reservoir (R-MCDI) to enrich phosphorus (P) from synthetic wastewater. This R-MCDI had two small-volume electrode chambers, and most of the electrolyte was contained in the reservoir, which was circulated along the electrode chambers. Compared with conventional MCDI, R-MCDI exhibited a phosphate removal rate of 0.052 μmol/(cm2·min), approximately double that of MCDI. This was attributed to R-MCDI's utilization of OH- alternative adsorption to remove phosphate from the influent. Noticing that around 73.9% of the removed phosphate was stored in the electrolyte in R-MCDI, we proposed a novel off-flow desorption operation to enrich the removed phosphate in the reservoir. Exciting results from the multicycle experiment (∼8 h) of R-MCDI showed that the PO43--P concentration in the reservoir increased all the way from the initial 152 mg/L to the final 361 mg/L, with the increase in the P charge efficiency from 5.5 to 22.9% and the decrease in the energy consumption from 28.2 to 6.8 kW h/kg P. The P recovery performance of R-MCDI was evaluated by viewing other similar studies, which revealed that R-MCDI in this study achieved superior P enrichment with low energy consumption and that the off-flow desorption proposed here considerably simplified the operation and enabled continuous P enrichment.

Electrochemical properties of MCDI-utilized PVA/SSA/GA cation exchange membrane

Membrane capacitive deionization (MCDI), an alternative desalination technology that uses a voltage between two electrodes that are covered with ion-exchange membranes to remove salt, has been drawing a lot of research attention. It has been demonstrated that the desalination performance in terms of salt removal and energy efficiency can be maximized when ion-exchange materials are incorporated on the electrodes in MCDI. In this study, the electrochemical properties of the MCDI electrodes coated with PVA/SSA/GA cation exchange membrane were intensively investigated, specifically the effect of sulfosuccinic acid (SSA) and glutaric anhydride (GA) content in the cross-linking reaction with polyvinyl alcohol (PVA). The presence of SSA in the cation exchange membrane helps improve its conductivity, as proven by the electrochemical measurements via cyclic voltammetry and galvanostatic charge-discharge. As a result, the salt adsorption capacity was also enhanced in the addition of SSA and GA into the PVA chain. The PVA/SSA/GA cation exchange membrane is proved to be an inexpensive, environmentally friendly and suitable candidate to be utilized in the MCDI systems. ® 2022 Journal of Science and Technology - NTTU

Fabrication of a new type of polyvinyl alcohol/sulfosuccinic acid/glutaric anhydride cation exchange membrane for desalination using membrane capacitive deionization

Nowadays, the lack of clean water is becoming a serious problem, due to the increasingdemand for clean water, along with global climate change. Desalination of sea water orbrackish water has been considered as a practicable method to supply clean water. Amongdesalination technologies, membrane capacitive deionization has emerged for the last 15years as an alternative method and received a lot of research attention since then. In thisstudy, low-cost and ecofriendly polyvinyl alcohol/sulfosuccinic acid/glutaric anhydridecomposite membranes were fabricated through the crosslinking reaction of sulfosuccinicacid and glutaric anhydride with polyvinyl alcohol. The effect of sulfosuccinic acid andglutaric anhydride content was investigated. The presence of SSA in the cation exchangemembrane, which was proven by FT-IR, helps improve its water uptake (98.5 % comparedto 38.2 %) as well as cation exchange capacity (1.993 mM/g compared to 0.156 mM/g).The polyvinyl alcohol/sulfosuccinic acid/glutaric anhydride composite solution wascoated on the electrode, and the membrane's ability to desalinate water was assessed. Themembrane-coated electrode exhibited enhanced salt adsorption capacity and shorterdesalination time (13.4 minutes compared to 85.3 minutes) in comparison with theuncoated commercial electrode, indicating that the polyvinyl alcohol/sulfosuccinicacid/glutaric anhydride membrane is a suitable candidate to be utilized in the membranecapacitive deionization systems.® 2022 Journal of Science and Technology - NTTU

A preliminary attempt at capacitive deionization with PVA/PSS gel coating as an alternative to ion exchange membrane

ABSTRACT PVA/PSS composite gel membrane electrode for membrane capacitive deionization (MCDI) was fabricated and characterised in the present study. The composite electrode with ion exchange surface is prepared by coating glutaraldehyde cross-linked polyvinyl alcohol (PVA) composite hydrogel, with Poly (Sodium 4-Styrenesulfonate) (PSS) added into the network, on the surface of activated carbon (AC) electrode. The feasibility of the gel membrane is analyzed by rheological, swelling rates and ion exchange capacity tests. Then electrochemical test and desalination test are used to study the performance of the MCDI electrode. The results show that coating of composite hydrogel layer improved the hydrophilicity, specific capacitance and lower interfacial electron transfer resistance of the electrode. Finally, we assemble the asymmetrical CDI cell with PVA/PSS composite gel electrode and AC electrode. Compared with the AC electrode, the salt adsorption capacity of PVA6-PSS15 can reach 18.9 mg g−1 and stable charge efficiency at 73.0% at operating voltage of 1.2 V. The decrease in specific capacitance of PVA6-PSS15 after 50 cycles is 1.33%, indicating that the electrode has a good cycling life. The gel membrane coated electrode prepared by PSS provides a new idea for the development of MCDI.

Development of Composite Nanostructured Electrodes for Water Desalination via Membrane Capacitive Deionization.

Novel two-layer nanostructured electrodes are successfully prepared for their application in membrane capacitive deionization (MCDI) processes. Nanostructured carbonaceous materials such as graphene oxide (GO) and carbon nanotubes (CNTs), as well as activated carbon (AC) are dispersed in a solution of poly(vinyl alcohol) (PVA), mixed with polyacrylic acid (PAA) or polydimethyldiallylammonium chloride (PDMDAAC), and subsequently cast on the top surface of an AC-based modified graphite electrode to form a thin composite layer that is cross-linked with glutaraldehyde (GA). Cyclic voltammetry (CV) is performed to investigate the electrochemical properties of the composite electrodes and desalination experiments are conducted in batch mode using a MCDI unit cell to investigate the effects of i) the nanostructured carbonaceous material, ii) its concentration in the polymer blend, and iii) the molecular weight of the polymers on the desalination efficiency of the system. Comparative studies with commercial membranes are performed proving that the composite nanostructured electrodes are more efficient in salt removal. The improved performance of the composite electrodes is attributed to the ion exchange properties of the selected polymers and the increased specific capacitance of the nanostructured carbonaceous materials. This research paves the way for wider application of MCDI in water desalination.

Preparation of heterogeneous cation exchange membrane and its contributions in enhancing the removal of Ni2+ by capacitive deionization system

Capacitive deionization (CDI), an emerging method to eliminate ions from water at a low cost, has garnered significant interest in recent years. This study evaluates the implication of cation exchange resin loading on the membrane via the nonsolvent-induced phase inversion method. After determining the quantity of resins efficiently loaded on the membrane, it was subsequently utilized as a cation exchange membrane in the membrane capacitive deionization (MCDI) unit to examine the performance removal of Ni2+. The results show that the amount of resins influenced the membrane structure and significantly improved the efficiency of Ni2+ removal. The sulfonic acid group show a strong intensity directly proportional to the quantity of resins based on the FTIR measurement. In conjunction with the enhanced resin amount, ion exchange capacity and water content were increased. Simultaneously, there was an observed elevation in the water contact angle and the roughness of the membrane surface with increased resin amount. In the MCDI unit, membrane M20 (20% by weight resin) was employed to elucidate its roles in the CDI unit, encompassing an examination of various concentrations and flow rates, with Ni2+ utilized as a test contaminant. The results demonstrated that using membrane M20 in the MCDI (MCDI-M20) unit consistently exhibited higher adsorption levels than the CDI unit, reaching 19.80 mg g−1 ACC in the MCDI-M20 unit, while CDI unit achieved 10.27 mg g−1 ACC at 200 mg L−1 Ni2+ concentration and a flow rate of 10 mL min−1 at 1.2 V. Additionally, Ni2+ concentrations and flow rates in CDI system had an evident impact on the duration of adsorption due to the mechanisms of ions transport on the membrane. This study suggests that employing the prepared membrane in the MCDI unit enhanced the removal of Ni2+ from the solution, contributing to sustainable development goals.

(Invited) Development and Scale-up of Membrane Capacitive Deionization (MCDI) for Desalination and Water Reuse

Desalination and water reuse are the key solutions to address global water scarcity. It is important to recognize the water-energy interactions and develop energy-efficient technologies to separate ions from brackish water, seawater and reclaimed wastewater. Most recently, membrane capacitive deionization (MCDI), inspired by energy storage devices (e.g., supercapacitors), is a promising desalination technology with several advantages of energy efficiency (TDS < 4000 ppm), high water recovery, less chemical additive, and environmental friendliness. In MCDI, ions are electrostatically captured within highly porous carbon electrodes through the formation of electrical double layer during the charging step, and then released into the solution by discharging the electrodes. By incorporating ion-exchange membranes (IEMs) in front of each electrode, the desalination performance can be significantly improved, achieving high salt adsorption capacity and charge efficiency. Over the past few years, we have made efforts to scale up the MCDI stacks for commercialization purposes, which are composed of 32 pairs of 400 mm × 200 mm activated carbon electrodes. Note that a stop-flow operation is applied in the discharge process to increase the water recovery (> 75%). A pilot-scale study of an MCDI system was performed to reclaim the secondary effluents from a municipal wastewater treatment plant. In addition, MCDI prototypes offer promising engineering opportunities for water recycling in high-tech industries, including reverse osmosis reject and wet scrubbing. Furthermore, we will discuss the challenges and perspectives for the future of MCDI as a cost-efficient, low-energy approach for desalination and resource recovery.